Files in this Data Supplement:

• Supplemental file 1 - Description of separation of centrally substituted LAS congeners and congener degradation and for generation of SPC and SPdC from 6-C_12- and 5-C₁₂-LAS or from 7-C₁₃-, 6-C₁₃-, and 5-C₁₃-LAS; HPLC-UV chromatograms of LAS in salts medium and of products detected after growth of strain DS-1 with those congeners of LAS (Fig. S1); HPLC-ESI-MS chromatograms of compounds in culture medium after growth of strain DS-1^T with 5-C₁₀-LAS, with 6-C₁₂- and 5-C₁₂-LAS, or with 7-C₁₃-, 6-C₁₃-, and 5-C₁₃-LAS (Fig. S2); HPLC-UV chromatograms of C₁₃-LAS material derived from preparative HPLC in culture medium and of SP(d)Cs generated during growth of strain DS-1 (Fig. S3).
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